High School

A boulder of mass 218 kg falls from a height of 19 m into a lake at a temperature of 16.4°C. Assume all the energy of the boulder transforms into thermal energy of the lake, which does not appreciably change temperature. Calculate the lake water's entropy change.

Answer :

The lake's entropy increases by approximately 139.56 J/K due to the boulder's impact.

To calculate the entropy change of the lake water due to the falling boulder, we can use the formula:

[tex]\[\Delta S = \frac{Q}{T}\][/tex]

Where:

  • [tex]\( \Delta S \)[/tex] is the change in entropy
  • [tex]\( Q \)[/tex] is the heat transferred to the lake water
  • [tex]\( T \)[/tex] is the temperature of the lake water

First, let's calculate the heat transferred to the lake water [tex](\( Q \))[/tex]. The potential energy of the boulder is converted into heat energy upon impact with the water. The potential energy is given by:

  • [tex]\[PE = mgh\][/tex]

Where:

  • [tex]\( m \)[/tex] is the mass of the boulder (218 kg)
  • [tex]\( g \)[/tex] is the acceleration due to gravity (approximately [tex]\(9.81 \, \text{m/s}^2\))[/tex]
  • [tex]\( h \)[/tex] is the height from which the boulder falls (19 m)

So,

  • [tex]\[PE = (218 \, \text{kg})(9.81 \, \text{m/s}^2)(19 \, \text{m})[/tex]

[tex]= 40402.62 \, \text{J}\][/tex]

This energy is transferred to the lake water as heat.

Now, we'll calculate the entropy change [tex](\( \Delta S \))[/tex]. We know that the temperature of the lake water [tex](\( T \))[/tex] is given as [tex]\(16.4°C\)[/tex], which we'll need to convert to Kelvin [tex](\( K \))[/tex] because temperature must be in Kelvin for entropy calculations.

  • [tex]\[T = 16.4°C + 273.15 = 289.55 \, K\][/tex]

Now, we can plug the values into the formula for entropy change:

  • [tex]\[\Delta S = \frac{Q}{T} \\[/tex]

[tex]= \frac{40402.62 \, \text{J}}{289.55 \, \text{K}}[/tex]

[tex]\approx 139.56 \, \text{J/K}\][/tex]

So, the entropy change of the lake water due to the falling boulder is approximately [tex]\(139.56 \, \text{J/K}\)[/tex].