Answer :
Final answer:
The single best answer is: Dimethylamine has hydrogen bonds, and the stronger intermolecular forces give it a higher boiling point.
Explanation:
The boiling point of a compound is influenced by the strength of the intermolecular forces between its molecules. In the case of trimethylamine and dimethylamine, the higher boiling point of dimethylamine, despite it having a lower molecular weight, can be attributed to its ability to form hydrogen bonds. This intermolecular attraction results from the presence of a hydrogen atom bonded to a nitrogen atom in dimethylamine, a condition necessary for hydrogen bonding. Trimethylamine, although heavier, does not feature these bonds and therefore boils at a lower temperature. Hence, it can be concluded that strong intermolecular attractions, such as hydrogen bonds, cause a higher boiling point.
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