High School

What volume of hydrogen gas is produced when 98.5 g of iron reacts completely according to the following reaction at 25°C and 1 atm?

\[ \text{iron (s) + hydrochloric acid (aq)} \rightarrow \text{iron(II) chloride (aq) + hydrogen (g)} \]

Calculate the volume of hydrogen gas in liters.

Answer :

Final answer:

The volume of hydrogen gas produced when 98.5 g of iron reacts completely is approximately 45.9 liters.

Explanation:

To calculate the volume of hydrogen gas produced, we need to follow these steps:

  1. Convert the mass of iron to moles using its molar mass.
  2. Use the molar ratio between iron and hydrogen gas to determine the moles of hydrogen gas produced.
  3. Apply the ideal gas law to convert the moles of hydrogen gas to volume.

Step 1: Convert the mass of iron to moles:

The molar mass of iron (Fe) is 55.845 g/mol. We can use this value to convert the mass of iron to moles:

moles of iron = mass of iron / molar mass of iron

moles of iron = 98.5 g / 55.845 g/mol

moles of iron ≈ 1.763 mol

Step 2: Use the molar ratio to determine the moles of hydrogen gas:

According to the balanced chemical equation, the molar ratio between iron and hydrogen gas is 1:1. This means that for every 1 mole of iron reacted, 1 mole of hydrogen gas is produced.

moles of hydrogen gas = moles of iron ≈ 1.763 mol

Step 3: Apply the ideal gas law to convert moles of hydrogen gas to volume:

The ideal gas law equation is PV = nRT, where P is the pressure, V is the volume, n is the number of moles, R is the ideal gas constant, and T is the temperature in Kelvin.

Since the pressure and temperature are given in the question (1 atm and 25°C), we can use these values in the equation:

V = (nRT) / P

Convert the temperature to Kelvin:

T = 25°C + 273.15 = 298.15 K

Substitute the values into the equation:

V = (1.763 mol * 0.0821 L·atm/(mol·K) * 298.15 K) / 1 atm

V ≈ 45.9 L

Therefore, the volume of hydrogen gas produced when 98.5 g of iron reacts completely is approximately 45.9 liters.

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